Layers of atmospheric pressure. Atmosphere of the earth

The Earth's atmosphere is a shell of air.

The presence of a special ball above the earth's surface was proven by the ancient Greeks, who called the atmosphere a steam or gas ball.

This is one of the geospheres of the planet, without which the existence of all living things would not be possible.

Where is the atmosphere

The atmosphere surrounds the planets with a dense layer of air, starting from earth's surface. It comes into contact with the hydrosphere, covers the lithosphere, extending far into outer space.

What does the atmosphere consist of?

The air layer of the Earth consists mainly of air, the total mass of which reaches 5.3 * 1018 kilograms. Of these, the diseased part is dry air, and much less is water vapor.

Over the sea, the density of the atmosphere is 1.2 kilograms per cubic meter. The temperature in the atmosphere can reach –140.7 degrees, air dissolves in water at zero temperature.

The atmosphere consists of several layers:

  • Troposphere;
  • Tropopause;
  • Stratosphere and stratopause;
  • Mesosphere and mesopause;
  • A special line above sea level called the Karman line;
  • Thermosphere and thermopause;
  • Scattering zone or exosphere.

Each layer has its own characteristics; they are interconnected and ensure the functioning of the planet’s air envelope.

Limits of the atmosphere

The lowest edge of the atmosphere passes through the hydrosphere and the upper layers of the lithosphere. The upper boundary begins in the exosphere, which is located 700 kilometers from the surface of the planet and will reach 1.3 thousand kilometers.

According to some reports, the atmosphere reaches 10 thousand kilometers. Scientists agreed that the upper boundary of the air layer should be the Karman line, since aeronautics is no longer possible here.

Thanks to constant study In this area, scientists have found that the atmosphere comes into contact with the ionosphere at an altitude of 118 kilometers.

Chemical composition

This layer of the Earth consists of gases and gaseous impurities, which include combustion residues, sea salt, ice, water, and dust. The composition and mass of gases that can be found in the atmosphere almost never changes, only the concentration of water and carbon dioxide changes.

The composition of the water can vary from 0.2 percent to 2.5 percent, depending on latitude. Additional elements are chlorine, nitrogen, sulfur, ammonia, carbon, ozone, hydrocarbons, hydrochloric acid, hydrogen fluoride, hydrogen bromide, hydrogen iodide.

A separate part is occupied by mercury, iodine, bromine, and nitric oxide. In addition, liquid and solid particles called aerosol are found in the troposphere. One of the rarest gases on the planet, radon, is found in the atmosphere.

In terms of chemical composition, nitrogen occupies more than 78% of the atmosphere, oxygen - almost 21%, carbon dioxide - 0.03%, argon - almost 1%, the total amount of the substance is less than 0.01%. This air composition was formed when the planet first emerged and began to develop.

With the advent of man, who gradually moved to production, chemical composition changed. In particular, the amount of carbon dioxide is constantly increasing.

Functions of the atmosphere

Gases in the air layer perform a variety of functions. Firstly, they absorb rays and radiant energy. Secondly, they influence the formation of temperature in the atmosphere and on Earth. Thirdly, it ensures life and its course on Earth.

In addition, this layer provides thermoregulation, which determines the weather and climate, the mode of heat distribution and atmospheric pressure. The troposphere helps regulate flows air masses, determine the movement of water, heat exchange processes.

The atmosphere constantly interacts with the lithosphere and hydrosphere, providing geological processes. Most main function is that there is protection from dust of meteorite origin, from the influence of space and the sun.

Facts

  • Oxygen provides the Earth with decomposition organic matter o hard rock, which is very important for emissions, decomposition of rocks, oxidation of organisms.
  • Carbon dioxide helps photosynthesis occur, and also contributes to the transmission of short waves of solar radiation and the absorption of long thermal waves. If this does not happen, then the so-called greenhouse effect is observed.
  • One of the main problems associated with the atmosphere is pollution, which occurs due to the operation of factories and automobile emissions. Therefore, many countries have introduced special environmental control, and at the international level special mechanisms are being undertaken to regulate emissions and the greenhouse effect.

Atmosphere (from ancient Greek ἀτμός - steam and σφαῖρα - ball) is a gas shell (geosphere) surrounding planet Earth. Its inner surface covers the hydrosphere and partially earth's crust, the outer one borders on the near-Earth part of outer space.

The set of branches of physics and chemistry that study the atmosphere is usually called atmospheric physics. The atmosphere determines the weather on the Earth's surface, meteorology studies weather, and climatology deals with long-term climate variations.

Physical properties

The thickness of the atmosphere is approximately 120 km from the Earth's surface. The total mass of air in the atmosphere is (5.1-5.3) 1018 kg. Of these, the mass of dry air is (5.1352 ± 0.0003) 1018 kg, the total mass of water vapor is on average 1.27 1016 kg.

The molar mass of clean dry air is 28.966 g/mol, and the density of air at the sea surface is approximately 1.2 kg/m3. The pressure at 0 °C at sea level is 101.325 kPa; critical temperature- −140.7 °C (~132.4 K); critical pressure - 3.7 MPa; Cp at 0 °C - 1.0048·103 J/(kg·K), Cv - 0.7159·103 J/(kg·K) (at 0 °C). Solubility of air in water (by mass) at 0 °C - 0.0036%, at 25 °C - 0.0023%.

For " normal conditions» at the Earth’s surface the following are accepted: density 1.2 kg/m3, barometric pressure 101.35 kPa, temperature plus 20 °C and relative humidity 50%. These conditional indicators have purely engineering significance.

Chemical composition

The Earth's atmosphere arose as a result of the release of gases during volcanic eruptions. With the advent of the oceans and the biosphere, it was formed due to gas exchange with water, plants, animals and the products of their decomposition in soils and swamps.

Currently, the Earth's atmosphere consists mainly of gases and various impurities (dust, water droplets, ice crystals, sea ​​salts, combustion products).

The concentration of gases that make up the atmosphere is almost constant, with the exception of water (H2O) and carbon dioxide (CO2).

Composition of dry air

Nitrogen
Oxygen
Argon
Water
Carbon dioxide
Neon
Helium
Methane
Krypton
Hydrogen
Xenon
Nitrous oxide

In addition to the gases indicated in the table, the atmosphere contains SO2, NH3, CO, ozone, hydrocarbons, HCl, HF, Hg vapor, I2, as well as NO and many other gases in small quantities. The troposphere constantly contains a large amount of suspended solid and liquid particles (aerosol).

The structure of the atmosphere

Troposphere

Its upper limit is at an altitude of 8-10 km in polar, 10-12 km in temperate and 16-18 km in tropical latitudes; lower in winter than in summer. The lower, main layer of the atmosphere contains more than 80% of the total mass atmospheric air and about 90% of all water vapor available in the atmosphere. Turbulence and convection are highly developed in the troposphere, clouds arise, and cyclones and anticyclones develop. Temperature decreases with increasing altitude with an average vertical gradient of 0.65°/100 m

Tropopause

The transition layer from the troposphere to the stratosphere, a layer of the atmosphere in which the decrease in temperature with height stops.

Stratosphere

A layer of the atmosphere located at an altitude of 11 to 50 km. Characterized by a slight change in temperature in the 11-25 km layer (lower layer of the stratosphere) and an increase in temperature in the 25-40 km layer from −56.5 to 0.8 ° C (upper layer of the stratosphere or inversion region). Having reached a value of about 273 K (almost 0 °C) at an altitude of about 40 km, the temperature remains constant up to an altitude of about 55 km. This region of constant temperature is called the stratopause and is the boundary between the stratosphere and mesosphere.

Stratopause

The boundary layer of the atmosphere between the stratosphere and mesosphere. In the vertical temperature distribution there is a maximum (about 0 °C).

Mesosphere

The mesosphere begins at an altitude of 50 km and extends to 80-90 km. Temperature decreases with height with an average vertical gradient of (0.25-0.3)°/100 m. The main energy process is radiant heat transfer. Complex photochemical processes involving free radicals, vibrationally excited molecules, etc. cause atmospheric luminescence.

Mesopause

Transitional layer between the mesosphere and thermosphere. There is a minimum in the vertical temperature distribution (about -90 °C).

Karman Line

The height above sea level, which is conventionally accepted as the boundary between the Earth's atmosphere and space. According to the FAI definition, the Karman line is located at an altitude of 100 km above sea level.

Boundary of the Earth's atmosphere

Thermosphere

The upper limit is about 800 km. The temperature rises to altitudes of 200-300 km, where it reaches values ​​of the order of 1500 K, after which it remains almost constant until high altitudes. Under the influence of ultraviolet and x-ray solar radiation and cosmic radiation, ionization of the air (“auroras”) occurs - the main regions of the ionosphere lie inside the thermosphere. At altitudes above 300 km, atomic oxygen predominates. The upper limit of the thermosphere is largely determined by the current activity of the Sun. During periods of low activity - for example, in 2008-2009 - there is a noticeable decrease in the size of this layer.

Thermopause

The region of the atmosphere adjacent to the thermosphere. In this area the absorption solar radiation insignificantly and the temperature does not actually change with altitude.

Exosphere (scattering sphere)

The exosphere is a dispersion zone, the outer part of the thermosphere, located above 700 km. The gas in the exosphere is very rarefied, and from here its particles leak into interplanetary space (dissipation).

Up to an altitude of 100 km, the atmosphere is a homogeneous, well-mixed mixture of gases. In higher layers, the distribution of gases by height depends on their molecular weights; the concentration of heavier gases decreases faster with distance from the Earth's surface. Due to the decrease in gas density, the temperature drops from 0 °C in the stratosphere to −110 °C in the mesosphere. However, the kinetic energy of individual particles at altitudes of 200-250 km corresponds to a temperature of ~150 °C. Above 200 km, significant fluctuations in temperature and density of gases in time and space are observed.

At an altitude of about 2000-3500 km, the exosphere gradually turns into the so-called near-space vacuum, which is filled with highly rarefied particles of interplanetary gas, mainly hydrogen atoms. But this gas represents only part of the interplanetary matter. The other part consists of dust particles of cometary and meteoric origin. In addition to extremely rarefied dust particles, electromagnetic and corpuscular radiation of solar and galactic origin penetrates into this space.

The troposphere accounts for about 80% of the mass of the atmosphere, the stratosphere - about 20%; the mass of the mesosphere is no more than 0.3%, the thermosphere is less than 0.05% of the total mass of the atmosphere. Based on the electrical properties in the atmosphere, the neutronosphere and ionosphere are distinguished. It is currently believed that the atmosphere extends to an altitude of 2000-3000 km.

Depending on the composition of the gas in the atmosphere, homosphere and heterosphere are distinguished. The heterosphere is an area where gravity affects the separation of gases, since their mixing at such a height is negligible. This implies a variable composition of the heterosphere. Below it lies a well-mixed, homogeneous part of the atmosphere called the homosphere. The boundary between these layers is called the turbopause; it lies at an altitude of about 120 km.

Other properties of the atmosphere and effects on the human body

Already at an altitude of 5 km above sea level, an untrained person begins to experience oxygen starvation and without adaptation, a person’s performance is significantly reduced. The physiological zone of the atmosphere ends here. Human breathing becomes impossible at an altitude of 9 km, although up to approximately 115 km the atmosphere contains oxygen.

The atmosphere supplies us with the oxygen necessary for breathing. However, due to the drop in the total pressure of the atmosphere as you rise to altitude, the partial pressure of oxygen decreases accordingly.

The human lungs constantly contain about 3 liters of alveolar air. The partial pressure of oxygen in alveolar air at normal atmospheric pressure is 110 mmHg. Art., carbon dioxide pressure - 40 mm Hg. Art., and water vapor - 47 mm Hg. Art. With increasing altitude, oxygen pressure drops, and the total vapor pressure of water and carbon dioxide in the lungs remains almost constant - about 87 mm Hg. Art. The supply of oxygen to the lungs will completely stop when the ambient air pressure becomes equal to this value.

At an altitude of about 19-20 km, the atmospheric pressure drops to 47 mm Hg. Art. Therefore, at this altitude, water and interstitial fluid begin to boil in the human body. Outside the pressurized cabin at these altitudes, death occurs almost instantly. Thus, from the point of view of human physiology, “space” begins already at an altitude of 15-19 km.

Dense layers of air - the troposphere and stratosphere - protect us from the damaging effects of radiation. With sufficient rarefaction of air, at altitudes of more than 36 km, ionizing radiation has an intense effect on the body - primary cosmic rays; At altitudes of more than 40 km, the ultraviolet part of the solar spectrum is dangerous for humans.

As we rise to an ever greater height above the Earth's surface, such familiar phenomena observed in the lower layers of the atmosphere as sound propagation, the occurrence of aerodynamic lift and drag, heat transfer by convection, etc. gradually weaken and then completely disappear.

In rarefied layers of air, sound propagation is impossible. Up to altitudes of 60-90 km, it is still possible to use air resistance and lift for controlled aerodynamic flight. But starting from altitudes of 100-130 km, the concepts of the M number and the sound barrier, familiar to every pilot, lose their meaning: there lies the conventional Karman line, beyond which the region of purely ballistic flight begins, which can only be controlled using reactive forces.

At altitudes above 100 km, the atmosphere is deprived of another remarkable property - the ability to absorb, conduct and transmit thermal energy by convection (i.e. by mixing air). This means that various elements of equipment on the orbital space station will not be able to be cooled from the outside in the same way as is usually done on an airplane - with the help of air jets and air radiators. At this altitude, as in space generally, the only way to transfer heat is thermal radiation.

History of atmospheric formation

According to the most common theory, the Earth's atmosphere has had three different compositions over time. Initially, it consisted of light gases (hydrogen and helium) captured from interplanetary space. This is the so-called primary atmosphere (about four billion years ago). At the next stage, active volcanic activity led to the saturation of the atmosphere with gases other than hydrogen (carbon dioxide, ammonia, water vapor). This is how the secondary atmosphere was formed (about three billion years before the present day). This atmosphere was restorative. Further, the process of atmosphere formation was determined by the following factors:

  • leakage of light gases (hydrogen and helium) into interplanetary space;
  • chemical reactions occurring in the atmosphere under the influence ultraviolet radiation, lightning discharges and some other factors.

Gradually, these factors led to the formation of a tertiary atmosphere, characterized by much less hydrogen and much more nitrogen and carbon dioxide (formed as a result of chemical reactions from ammonia and hydrocarbons).

Nitrogen

The formation of a large amount of nitrogen N2 is due to the oxidation of the ammonia-hydrogen atmosphere by molecular oxygen O2, which began to come from the surface of the planet as a result of photosynthesis, starting 3 billion years ago. Nitrogen N2 is also released into the atmosphere as a result of denitrification of nitrates and other nitrogen-containing compounds. Nitrogen is oxidized by ozone to NO in the upper atmosphere.

Nitrogen N2 reacts only under specific conditions (for example, during a lightning discharge). Oxidation of molecular nitrogen with ozone during electrical discharges in small quantities is used in industrial production nitrogen fertilizers. Cyanobacteria (blue-green algae) and nodule bacteria that form rhizobial symbiosis with leguminous plants, the so-called, can oxidize it with low energy consumption and convert it into a biologically active form. green manure.

Oxygen

The composition of the atmosphere began to change radically with the appearance of living organisms on Earth, as a result of photosynthesis, accompanied by the release of oxygen and the absorption of carbon dioxide. Initially, oxygen was spent on the oxidation of reduced compounds - ammonia, hydrocarbons, ferrous form of iron contained in the oceans, etc. At the end of this stage, the oxygen content in the atmosphere began to increase. Gradually, a modern atmosphere with oxidizing properties formed. Since this caused serious and abrupt changes in many processes occurring in the atmosphere, lithosphere and biosphere, this event was called the Oxygen Catastrophe.

During the Phanerozoic, the composition of the atmosphere and oxygen content underwent changes. They correlated primarily with the rate of deposition of organic sediment. Thus, during periods of coal accumulation, the oxygen content in the atmosphere apparently significantly exceeded the modern level.

Carbon dioxide

The CO2 content in the atmosphere depends on volcanic activity and chemical processes in the earth's shells, but most of all - on the intensity of biosynthesis and decomposition of organic matter in the Earth's biosphere. Almost the entire current biomass of the planet (about 2.4 1012 tons) is formed due to carbon dioxide, nitrogen and water vapor contained in the atmospheric air. Organics buried in the ocean, swamps and forests turn into coal, oil and natural gas.

Noble gases

The source of noble gases - argon, helium and krypton - is volcanic eruptions and the decay of radioactive elements. The Earth in general and the atmosphere in particular are depleted of inert gases compared to space. It is believed that the reason for this lies in the continuous leakage of gases into interplanetary space.

Air pollution

IN lately Man began to influence the evolution of the atmosphere. The result of his activities was a constant increase in the content of carbon dioxide in the atmosphere due to the combustion of hydrocarbon fuels accumulated in previous geological eras. Huge amounts of CO2 are consumed during photosynthesis and absorbed by the world's oceans. This gas enters the atmosphere due to the decomposition of carbonate rocks and organic substances of plant and animal origin, as well as due to volcanism and human industrial activity. Over the past 100 years, the CO2 content in the atmosphere has increased by 10%, with the bulk (360 billion tons) coming from fuel combustion. If the growth rate of fuel combustion continues, then in the next 200-300 years the amount of CO2 in the atmosphere will double and could lead to global climate change.

Fuel combustion is the main source of polluting gases (CO, NO, SO2). Sulfur dioxide is oxidized by atmospheric oxygen to SO3, and nitrogen oxide to NO2 in the upper layers of the atmosphere, which in turn interact with water vapor, and the resulting sulfuric acid H2SO4 and nitric acid HNO3 falls on the Earth's surface in the form of the so-called. acid rain. Using motors internal combustion leads to significant atmospheric pollution with nitrogen oxides, hydrocarbons and lead compounds (tetraethyl lead) Pb(CH3CH2)4.

Aerosol pollution of the atmosphere is caused by both natural causes (volcanic eruptions, dust storms, entrainment of droplets of sea water and plant pollen, etc.) and economic activity people (ore mining and building materials, fuel combustion, cement production, etc.). Intensive large-scale emission of solid particles into the atmosphere is one of the possible reasons changes in the planet's climate.

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    Subtitles

Atmospheric boundary

The atmosphere is considered to be that region around the Earth in which the gaseous medium rotates together with the Earth as a single whole. The atmosphere passes into interplanetary space gradually, in the exosphere, starting at an altitude of 500-1000 km from the Earth's surface.

According to the definition proposed by the International Aviation Federation, the boundary of the atmosphere and space is drawn along the Karman line, located at an altitude of about 100 km, above which aviation flights become completely impossible. NASA uses the 122 kilometers (400,000 ft) mark as the atmospheric limit, where the shuttles switch from powered maneuvering to aerodynamic maneuvering.

Physical properties

In addition to the gases indicated in the table, the atmosphere contains Cl 2 (\displaystyle (\ce (Cl2))) , SO 2 (\displaystyle (\ce (SO2))) , NH 3 (\displaystyle (\ce (NH3))) , CO (\displaystyle ((\ce (CO)))) , O 3 (\displaystyle ((\ce (O3)))) , NO 2 (\displaystyle (\ce (NO2))), hydrocarbons, HCl (\displaystyle (\ce (HCl))) , HF (\displaystyle (\ce (HF))) , HBr (\displaystyle (\ce (HBr))) , HI (\displaystyle ((\ce (HI)))), couples Hg (\displaystyle (\ce (Hg))) , I 2 (\displaystyle (\ce (I2))) , Br 2 (\displaystyle (\ce (Br2))), as well as many other gases in small quantities. The troposphere constantly contains a large amount of suspended solid and liquid particles (aerosol). The rarest gas in Earth's atmosphere is Rn (\displaystyle (\ce (Rn))) .

The structure of the atmosphere

Atmospheric boundary layer

The lower layer of the troposphere (1-2 km thick), in which the state and properties of the Earth's surface directly affect the dynamics of the atmosphere.

Troposphere

Its upper limit is at an altitude of 8-10 km in polar, 10-12 km in temperate and 16-18 km in tropical latitudes; lower in winter than in summer.
The lower, main layer of the atmosphere contains more than 80% of the total mass of atmospheric air and about 90% of all water vapor present in the atmosphere. Turbulence and convection are highly developed in the troposphere, clouds appear, and cyclones and anticyclones develop. Temperature decreases with increasing altitude with an average vertical gradient of 0.65°/100 meters.

Tropopause

The transition layer from the troposphere to the stratosphere, a layer of the atmosphere in which the decrease in temperature with height stops.

Stratosphere

A layer of the atmosphere located at an altitude of 11 to 50 km. Characterized by a slight change in temperature in the 11-25 km layer (lower layer of the stratosphere) and an increase in the 25-40 km layer from minus 56.5 to plus 0.8 ° C (upper layer of the stratosphere or inversion region). Having reached a value of about 273 K (almost 0 °C) at an altitude of about 40 km, the temperature remains constant up to an altitude of about 55 km. This region of constant temperature is called the stratopause and is the boundary between the stratosphere and mesosphere.

Stratopause

The boundary layer of the atmosphere between the stratosphere and mesosphere. In the vertical temperature distribution there is a maximum (about 0 °C).

Mesosphere

Thermosphere

The upper limit is about 800 km. The temperature rises to altitudes of 200-300 km, where it reaches values ​​of the order of 1500 K, after which it remains almost constant to high altitudes. Under the influence of solar radiation and cosmic radiation, ionization of the air (“auroras”) occurs - the main regions of the ionosphere lie inside the thermosphere. At altitudes above 300 km, atomic oxygen predominates. The upper limit of the thermosphere is largely determined by the current activity of the Sun. During periods of low activity - for example, in 2008-2009 - there is a noticeable decrease in the size of this layer.

Thermopause

The region of the atmosphere adjacent above the thermosphere. In this region, the absorption of solar radiation is negligible and the temperature does not actually change with altitude.

Exosphere (scattering sphere)

Up to an altitude of 100 km, the atmosphere is a homogeneous, well-mixed mixture of gases. In higher layers, the distribution of gases by height depends on their molecular weights; the concentration of heavier gases decreases faster with distance from the Earth's surface. Due to the decrease in gas density, the temperature drops from 0 °C in the stratosphere to minus 110 °C in the mesosphere. However, the kinetic energy of individual particles at altitudes of 200-250 km corresponds to a temperature of ~ 150 °C. Above 200 km, significant fluctuations in temperature and density of gases in time and space are observed.

At an altitude of about 2000-3500 km, the exosphere gradually turns into the so-called near space vacuum, which is filled with rare particles of interplanetary gas, mainly hydrogen atoms. But this gas represents only part of the interplanetary matter. The other part consists of dust particles of cometary and meteoric origin. In addition to extremely rarefied dust particles, electromagnetic and corpuscular radiation of solar and galactic origin penetrates into this space.

Review

The troposphere accounts for about 80% of the mass of the atmosphere, the stratosphere - about 20%; the mass of the mesosphere is no more than 0.3%, the thermosphere is less than 0.05% of the total mass of the atmosphere.

Based on electrical properties in the atmosphere, they distinguish neutrosphere And ionosphere .

Depending on the composition of the gas in the atmosphere, they emit homosphere And heterosphere. Heterosphere- This is the area where gravity affects the separation of gases, since their mixing at such an altitude is negligible. This implies a variable composition of the heterosphere. Below it lies a well-mixed, homogeneous part of the atmosphere, called the homosphere. The boundary between these layers is called the turbopause, it lies at an altitude of about 120 km.

Other properties of the atmosphere and effects on the human body

Already at an altitude of 5 km above sea level, an untrained person begins to experience oxygen starvation and without adaptation, a person’s performance is significantly reduced. The physiological zone of the atmosphere ends here. Human breathing becomes impossible at an altitude of 9 km, although up to approximately 115 km the atmosphere contains oxygen.

The atmosphere supplies us with the oxygen necessary for breathing. However, due to the drop in the total pressure of the atmosphere as you rise to altitude, the partial pressure of oxygen decreases accordingly.

History of atmospheric formation

According to the most common theory, the Earth's atmosphere has had three different compositions throughout its history. Initially, it consisted of light gases (hydrogen and helium) captured from interplanetary space. This is the so-called primary atmosphere. At the next stage, active volcanic activity led to the saturation of the atmosphere with gases other than hydrogen (carbon dioxide, ammonia, water vapor). This is how it was formed secondary atmosphere. This atmosphere was restorative. Further, the process of atmosphere formation was determined by the following factors:

  • leakage of light gases (hydrogen and helium) into interplanetary space;
  • chemical reactions occurring in the atmosphere under the influence of ultraviolet radiation, lightning discharges and some other factors.

Gradually these factors led to the formation tertiary atmosphere, characterized by a much lower content of hydrogen and a much higher content of nitrogen and carbon dioxide (formed as a result of chemical reactions from ammonia and hydrocarbons).

Nitrogen

The formation of a large amount of nitrogen is due to the oxidation of the ammonia-hydrogen atmosphere by molecular oxygen O 2 (\displaystyle (\ce (O2))), which began to come from the surface of the planet as a result of photosynthesis, starting 3 billion years ago. Also nitrogen N 2 (\displaystyle (\ce (N2))) released into the atmosphere as a result of denitrification of nitrates and other nitrogen-containing compounds. Nitrogen is oxidized by ozone to NO (\displaystyle ((\ce (NO)))) in the upper layers of the atmosphere.

Nitrogen N 2 (\displaystyle (\ce (N2))) reacts only under specific conditions (for example, during a lightning discharge). The oxidation of molecular nitrogen by ozone during electrical discharges is used in small quantities in the industrial production of nitrogen fertilizers. Cyanobacteria (blue-green algae) and nodule bacteria, which form rhizobial symbiosis with leguminous plants, which can be effective green manures - plants that do not deplete, but enrich the soil with natural fertilizers, can oxidize it with low energy consumption and convert it into a biologically active form.

Oxygen

The composition of the atmosphere began to change radically with the appearance of living organisms on Earth as a result of photosynthesis, accompanied by the release of oxygen and the absorption of carbon dioxide. Initially, oxygen was spent on the oxidation of reduced compounds - ammonia, hydrocarbons, ferrous form of iron contained in the oceans and others. At the end of this stage, the oxygen content in the atmosphere began to increase. Gradually, a modern atmosphere with oxidizing properties formed. Since this caused serious and abrupt changes in many processes occurring in the atmosphere, lithosphere and biosphere, this event was called the Oxygen Catastrophe.

Noble gases

Air pollution

Recently, humans have begun to influence the evolution of the atmosphere. The result of human activity has been a constant increase in the content of carbon dioxide in the atmosphere due to the combustion of hydrocarbon fuels accumulated in previous geological eras. Enormous quantities are consumed during photosynthesis and are absorbed by the world's oceans. This gas enters the atmosphere due to the decomposition of carbonate rocks and organic substances of plant and animal origin, as well as due to volcanism and human industrial activity. Over the last 100 years content CO 2 (\displaystyle (\ce (CO2))) in the atmosphere increased by 10%, with the bulk (360 billion tons) coming from fuel combustion. If the growth rate of fuel combustion continues, then in the next 200-300 years the amount CO 2 (\displaystyle (\ce (CO2))) in the atmosphere will double and may lead to

Composition of the atmosphere. The air envelope of our planet - atmosphere protects the earth's surface from the harmful effects of ultraviolet radiation from the Sun on living organisms. It also protects the Earth from cosmic particles - dust and meteorites.

The atmosphere consists of a mechanical mixture of gases: 78% of its volume is nitrogen, 21% is oxygen and less than 1% is helium, argon, krypton and other inert gases. The amount of oxygen and nitrogen in the air is practically unchanged, because nitrogen almost does not combine with other substances, and oxygen, which, although very active and spent on respiration, oxidation and combustion, is constantly replenished by plants.

Up to an altitude of approximately 100 km, the percentage of these gases remains virtually unchanged. This is due to the fact that the air is constantly mixed.

In addition to the mentioned gases, the atmosphere contains about 0.03% carbon dioxide, which is usually concentrated near the earth's surface and is distributed unevenly: in cities, industrial centers and areas of volcanic activity, its amount increases.

There is always a certain amount of impurities in the atmosphere - water vapor and dust. The content of water vapor depends on the air temperature: the higher the temperature, the more vapor the air can hold. Due to the presence of vaporous water in the air, atmospheric phenomena such as rainbows, refraction of sunlight, etc. are possible.

Dust enters the atmosphere during volcanic eruptions, sand and dust storms, during incomplete combustion of fuel at thermal power plants, etc.

The structure of the atmosphere. The density of the atmosphere changes with altitude: it is highest at the Earth's surface and decreases as it goes up. Thus, at an altitude of 5.5 km, the density of the atmosphere is 2 times, and at an altitude of 11 km, it is 4 times less than in the surface layer.

Depending on the density, composition and properties of gases, the atmosphere is divided into five concentric layers (Fig. 34).

Rice. 34. Vertical section of the atmosphere (stratification of the atmosphere)

1. The bottom layer is called troposphere. Its upper boundary passes at an altitude of 8-10 km at the poles and 16-18 km at the equator. The troposphere contains up to 80% of the total mass of the atmosphere and almost all water vapor.

The air temperature in the troposphere decreases with height by 0.6 °C every 100 m and at its upper boundary is -45-55 °C.

The air in the troposphere is constantly mixed and moves in different directions. Only here are fogs, rains, snowfalls, thunderstorms, storms and other weather phenomena observed.

2. Located above stratosphere, which extends to an altitude of 50-55 km. Air density and pressure in the stratosphere are negligible. Thin air consists of the same gases as in the troposphere, but it contains more ozone. The highest concentration of ozone is observed at an altitude of 15-30 km. The temperature in the stratosphere increases with altitude and at its upper boundary reaches 0 °C and above. This is because ozone absorbs short-wave energy from the sun, causing the air to warm up.

3. Lies above the stratosphere mesosphere, extending to an altitude of 80 km. There the temperature drops again and reaches -90 °C. The air density there is 200 times less than at the surface of the Earth.

4. Above the mesosphere is located thermosphere(from 80 to 800 km). The temperature in this layer increases: at an altitude of 150 km to 220 °C; at an altitude of 600 km up to 1500 °C. Atmospheric gases (nitrogen and oxygen) are in an ionized state. Under the influence of short-wave solar radiation, individual electrons are separated from the shells of atoms. As a result, in this layer - ionosphere layers of charged particles appear. Their densest layer is located at an altitude of 300-400 km. Due to the low density, the sun's rays are not scattered there, so the sky is black, stars and planets shine brightly on it.

In the ionosphere there are polar lights, powerful electric currents that cause disturbances magnetic field Earth.

5. Above 800 km is the outer shell - exosphere. The speed of movement of individual particles in the exosphere is approaching critical - 11.2 mm/s, so individual particles can overcome gravity and escape into outer space.

The meaning of atmosphere. The role of the atmosphere in the life of our planet is exceptionally great. Without her, the Earth would be dead. The atmosphere protects the Earth's surface from extreme heating and cooling. Its effect can be likened to the role of glass in greenhouses: allowing the sun's rays to pass through and preventing heat loss.

The atmosphere protects living organisms from short-wave and corpuscular radiation from the Sun. The atmosphere is the environment where weather phenomena occur, with which all human activity is associated. The study of this shell is carried out at meteorological stations. Day and night, in any weather, meteorologists monitor the state of the lower layer of the atmosphere. Four times a day, and at many stations hourly they measure temperature, pressure, air humidity, note cloudiness, wind direction and speed, amount of precipitation, electrical and sound phenomena in the atmosphere. Meteorological stations are located everywhere: in Antarctica and in tropical rainforests, on high mountains and in vast expanses of tundra. Observations are also carried out on the oceans from specially built ships.

Since the 30s. XX century observations began in the free atmosphere. They began to launch radiosondes that rise to a height of 25-35 km and, using radio equipment, transmit information about temperature, pressure, air humidity and wind speed to Earth. Nowadays, meteorological rockets and satellites are also widely used. The latter have television installations that transmit images of the earth's surface and clouds.

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5. The air shell of the earth§ 31. Heating of the atmosphere